Product ID:93512, 25-052
MSDS Date:01/29/1994
FSC:9150
NIIN:00N018291
MSDS Number: CCVYR

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

WASTE RESIDUES OF THIS PRODUCT.

RTECS: 9999999ZZ

REFER TO SECTION ON SPECIAL PROTECTION

RTECS: 9999999ZZ

SKIN THOROUGHLY W/SOAP & WATER. REMOVE SOILED

RTECS: 9999999ZZ

CERTAIN COMPONENTS BELOW MANDATED STANDARDS, AS

RTECS: 9999999ZZ

AUTHORITIES BEFORE REUSING, RECONDITIONING,

RTECS: 9999999ZZ

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-88-4

RTECS: PY8040501

Fraction By Weight: 70-80%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL, RAT) >15

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

(REFINED PETROLEUM OIL)

CAS: 64742-01-4

OSHA PEL N/K

ACGIH TLV: N/K

STODDARD SOLVENT; (MINERAL SPIRITS)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <25.0%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

LOW ASH ADDITIVE MIXTURE

Fraction By Weight: <10%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL, RAT) 60.3 G/KG

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

RUST INHIBITOR; (RUST PREVENTIVE SYNERGIST)

Fraction By Weight: <0.5%

OSHA PEL N/K

ACGIH TLV: N/K

DYE

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

FOLLOWING

RTECS: 9999999ZZ

THERE EXISTS STILL SOME RISK OF ASPIR INTO THE

RTECS: 9999999ZZ

ASPIRATED MATL MAY CAUSE CHEMICAL PNEUMONITIS OR

RTECS: 9999999ZZ

INJECTION REQUIRES PROMPT SURGICAL DEBRIDEMENT. IF

RTECS: 9999999ZZ

WHICH COULD INCLUDE FLAMMABLE OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LOW RISK OF INHALATION.
IN ENCLSD SPACES OR WHERE HOT, VAPS MAY REACH CONCS SUFFICIENT TO
CAUSE DROWSINESS, DIZZINESS, HEADACHE, NAUSEA OR LUNG IRRIT. MISTS
ABOVE TLV MAY CAUSE CHEM PNEU MONITIS. SKIN: MILD IRRITANT. EYES:
MILDLY IRRITATING. INGEST: TOXICITY IS RELATIVELY LOW, HOWEVER,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OF SAYBOLT VISCOSITY OF ABOUT 195
(100F), THERE EXISTS STILL SOME RISK OF ASPIR INTO LUNGS. ON INGEST
OF LG QTYS, SLIGHT GI DISCOMFORT, DIARRHEA & HEADACHE MAY OCCUR.
SMALL DOSES MAY PRODUCE IRRIT & DIARRHEA. INJECTION: SUBCUTANEOUS
OR INTRAMUSCULAR INJECTION SHOULD BE CONSIDERED MED EMER. CHRONIC:
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL: REMOVE TO FRESH AIR. NISOH APPRVD RESPIRATORY SUPPORT,
IF NECESSARY. SEEK MEDICAL AID. SKIN: WASH W/SOAP & WATER. DO NOT
WEAR HEAVILY CONTAMD CLTHG BEFORE LAUNDERING. EYES: FLUSH W/LARGE
VOLUME S OF WATER FOR AT LEAST 15 MINUTES. SEEK MD IF ANY
COMPLICATIONS ARISE. INGEST: DO NOT INDUCE VOMITING. SEEK MEDICAL
AID. INJECTION: SUBCUTANEOUS INJECTION IS MEDICAL EMERGENCY. SEEK
MEDICAL (ING 9)

Flash Point Method:PMCC
Flash Point:147F,64C
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNIT, PROVIDE
ADEQUATE VENT, CONTAIN LEAK. SMALL SPILLS: ABSORB W/SUITABLE MATL
SUCH AS RAGS, STRAW OR SAND. LARGE SPILLS: CONTAIN SPILL IN EARTHEN
DIKES FOR LATER RECOVERY. REPORT SPILLS AS REQD TO APPROP
AUTHORITIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BELOW 150F. DO NOT APPLY HIGH
HEAT OR FLAME TO CNTNR. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS.
EMPTY CNTNRS MAY CONTAIN PROD RESIDUE (ING 13)
Other Precautions:COMBUSTIBLE LIQUID. DO NOT INHALE VAPORS NOR PERMIT
DIRECT DERMAL CONTACT. HARMFUL OR FATAL IF SWALLOWED. DO NOT INDUCE
VOMITING. CALL MD IMMED. KEEP OUT OF REACH OF CHILDREN. PROT
MEASURES DURING REP AIR & MAINT OF CONTAMD EQUIP: (ING 16)

Respiratory Protection:NORMALLY NONE REQUIRED. IF HIGH VAPOR OR MIST
CONCENTRATIONS EXPECTED, USE NIOSH APPROVED RESPIRATOR APPROVED FOR
ORGANIC VAPORS AND MISTS.
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECHANICAL
VENTILATION MAY BE REQUIRED TO KEEP LEVELS OF (ING 18)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNGD/RPTD EXPOSURE.
Work Hygienic Practices:LAUNDER SOILED WORK CLOTHES BEFORE REUSE.
Supplemental Safety and Health
FL PT: 180F,82C. FL PT METH: COC. EFTS OF OVEREXP: PRLNGD &/OR FREQUENT
DERMAL CONTACT MAY CAUSE DRYING, CRACKING (DERMATITIS) OR
FOLLICULITIS. RPTD, EXCESS EXPOS TO MISTS/FUMES MAY INDUCE
PULMONARY I RRIT OR CHRONIC BRONCHITIS. TOXICITY:SLIGHTLY TO
MODERATLEY TOX. LETHAL DOSE OF 150 LB HUMAN ADULT MAY BE 10 TO 250
ML.

Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<20
Vapor Density:>1
Spec Gravity:0.86 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLUE-GREEN LIQUID; SLIGHT ODOR OF PETROLEUM
DISTILLATE.
Percent Volatiles by Volume:<20

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE (CARBON MONOXIDE UNDER
INCOMPLETE COMBUSTION).

Waste Disposal Methods:IT IS RESPONSIBILITY OF USER TO DETERMINE IF THE
MATL IS A HAZARDOUS WASTE AT THE TIME OF DISPOSAL. CHECK BEFORE
DISPOSING TO BE SURE OF COMPLIANCE W/ALL APPLIC FEDERAL, STATE &
LOCAL LAWS & REGULATIO NS. RCRA EMERGENCY HOTLINE NUMBER:
800-424-9346.

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particular situation.